
Answer
🌡️ Analysis of Alpha (Fractional) Diagram for Polyprotic Acid
🔬 Understanding the Diagram:
The alpha diagram shows the relative abundance (% species) of different ionic forms of a polyprotic acid as a function of pH. In this case, the number of distinct curves (4 total) indicates the presence of 3 acidic protons.
- At low pH (0–2): One dominant species → fully protonated form:
H₃A - Around pH 3–5: Second species dominates →
H₂A⁻ - Around pH 6–8: Third species dominates →
HA²⁻ - At high pH (10+): Fully deprotonated species:
A³⁻
Therefore, the acid releases 3 protons in stepwise fashion, confirming it is triprotic.
📍 What is the dominant species at pH 4?
At pH 4, the orange curve is the dominant peak. This corresponds to the second species, H₂A⁻, where one proton has been lost.
✅ Correct Answer: A – 3 acidic protons, H2A−
