Provide an IUPAC name for the structure shown. (Do not use stereochemical terms in the name

Answer

2,2,5,5-Tetramethylhex-3-yne – IUPAC Naming Explained

IUPAC Name: 2,2,5,5-Tetramethylhex-3-yne

This article explains the step-by-step process to determine the IUPAC name of a hydrocarbon with multiple substituents and a triple bond.

๐Ÿ”ฌ Step 1: Identify the Parent Chain

The longest continuous carbon chain that includes the triple bond has 6 carbon atoms. Hence, the root name is hex. Because of the triple bond, we use the suffix -yne, making it hexyne.

๐Ÿ”ข Step 2: Number the Carbon Chain

The carbon chain is numbered to give the triple bond the lowest number. The triple bond lies between carbon atoms 3 and 4, resulting in the name hex-3-yne.

๐ŸŒฟ Step 3: Identify Substituents

There are four methyl groups:

  • Two methyl groups at carbon 2
  • Two methyl groups at carbon 5

Total: 2,2,5,5-tetramethyl

๐Ÿงช Step 4: Assemble the Name

Combining the information:

Final IUPAC Name: 2,2,5,5-Tetramethylhex-3-yne

โœ… Summary

  • Parent Chain: 6 carbon atoms โ†’ hex
  • Triple bond at C-3: hex-3-yne
  • Substituents: Four methyl groups โ†’ tetramethyl
  • Positions: 2,2,5,5

This is a clear example of how substituent positions and bond types influence the structure’s systematic IUPAC name.

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