Predict the FINAL (?) product for each of the following reaction or synthetic chain:1.H-N(6)2. H2O?CrO,ClABCDPredict the FINAL (?) product f

Predict the FINAL (?) product for each of the following reaction or synthetic chain:1.H-N(6)2. H2O?CrO,ClABCDPredict the FINAL (?) product f

Answer

Predicting Final Product of a Multi-Step Organic Reaction

Prediction of Final Product in a Multi-Step Organic Reaction

Step 1: Grignard Reaction

Reacting benzaldehyde with phenyl magnesium bromide (PhMgBr) followed by water results in a Grignard addition reaction.

  • Phenyl group (Ph⁻) acts as a nucleophile.
  • It attacks the electrophilic carbon of the aldehyde group.
  • After protonation, a secondary alcohol is formed: diphenylmethanol (Ph2CHOH).

Intermediate: Diphenylmethanol

Step 2: Oxidation with PCC (pyridinium chlorochromate)

The alcohol undergoes mild oxidation using PCC (in the presence of CrO3 and pyridine).

  • PCC oxidizes secondary alcohols to ketones.
  • The hydroxyl group of diphenylmethanol is converted into a carbonyl group (C=O).

Intermediate: Benzophenone (Ph2CO)

Step 3: Oxidation with Na2Cr2O7 / H2SO4

This step typically performs strong oxidation, especially of benzylic positions or alcohols. However:

  • Benzophenone is a ketone and cannot be oxidized further under these conditions.
  • Therefore, the molecule remains unchanged in this step.

Final Product: Benzophenone (Ph2CO)

Correct Option: A

Option A shows benzophenone, which is the correct final product.

✔️ Answer: Option A

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