
Answer
Hydrogen-like Ions: Energy and Radius
For hydrogen-like ions, the total energy and orbit radius are given by:
Total Energy:
En = -RH Z2 / n2
Orbit Radius:
rn = a0 n2 / Z
Where:
- En is the energy of the electron
- RH is the Rydberg constant (≈ 2.18 × 10-18 J)
- Z is the atomic number
- n is the principal quantum number
- a0 is the Bohr radius (≈ 52.9 pm)
Examples (for n = 1):
He+ (Z = 2):
E = -8.72 × 10-18 J
r = 26.4 pm
Li2+ (Z = 3):
E = -19.62 × 10-18 J
r = 17.6 pm
As the atomic number Z increases, the energy becomes more negative and the orbit radius decreases.
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