For many purposes we can treat methane (CH) as an ideal gas at temperatures – Free 4A

For many purposes we can treat methane (CH) as an ideal gas at temperatures above its boiling point of – 161. °C. Suppose the temperature of

For many purposes we can treat methane (CH) as an ideal gas at temperatures - Free 4A

Answer

Methane Gas Volume Change Analysis

Methane Gas Volume Change Analysis

Context

We examine how the volume of methane gas changes under different combinations of pressure and temperature changes using the ideal gas law:


  V₂ / V₁ = (P₁ / P₂) × (T₂ / T₁)
  

In the original scenario:

  • Temperature: increased from −72.0°C (201.15 K) to −62.0°C (211.15 K)
  • Pressure: increased by 15% → P₂ = 1.15 × P₁
  • Result: Volume decreased by approximately 8.75%
✅ A similar change in magnitude, but with pressure decreasing instead of increasing, would lead to a volume increase.

Alternative Scenario

  • Same temperature change: −72.0°C to −62.0°C
  • Pressure decreases by 15%: P₂ = 0.85 × P₁

Calculation:


  V₂ / V₁ = (1 / 0.85) × (211.15 / 201.15) ≈ 1.1765 × 1.0498 ≈ 1.235
  

Percentage change in volume:


  (1.235 - 1) × 100 = 23.5%
  

Comparison Table

Scenario Pressure Change Temperature Change Volume Change
Original Case +15% −72°C → −62°C −8.75%
Reversed Pressure −15% −72°C → −62°C +23.5%

Conclusion

A similar degree of pressure change in the opposite direction (from an increase to a decrease), combined with the same temperature increase, results in a volume increase rather than a decrease.

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