HBrO2. Show the reaction with H+ (aq) as a product. HBrO2. Show the reaction with the hydronium ion as a product. C2H5COOH. Show the reaction with H+ (aq) as a product. C2H5COOH. Show the reaction with the hydronium ion as a product.
Answer
Acid Reactions of HBrO₂ and C₂H₅COOH with Water: Formation of H⁺ and H₃O⁺
Acids in aqueous solutions can donate protons (H⁺), which may appear either as free hydrogen ions (H⁺) or as part of the hydronium ion (H₃O⁺) when reacting with water. Let’s examine how two acids—bromous acid (HBrO₂) and propanoic acid (C₂H₅COOH)—behave in aqueous environments.
🧪 Reaction of HBrO₂ Showing H⁺ (aq) as Product
Bromous acid (HBrO₂) is a weak acid that dissociates partially in water. The dissociation can be represented as:
HBrO₂ (aq) ⇌ H⁺ (aq) + BrO₂⁻ (aq)
Here, the acid donates a proton (H⁺) to the solution, producing a hydrogen ion and the conjugate base bromite ion (BrO₂⁻).
💧 Reaction of HBrO₂ Showing Hydronium Ion (H₃O⁺) as Product
When considering water as the base (as per the Brønsted-Lowry definition), the H⁺ ion doesn’t exist freely but rather associates with water to form hydronium (H₃O⁺):
HBrO₂ (aq) + H₂O (l) ⇌ H₃O⁺ (aq) + BrO₂⁻ (aq)
This form is more chemically accurate in aqueous solutions.
🧪 Reaction of C₂H₅COOH Showing H⁺ (aq) as Product
Propanoic acid (C₂H₅COOH) is also a weak acid that partially ionizes:
C₂H₅COOH (aq) ⇌ H⁺ (aq) + C₂H₅COO⁻ (aq)
The hydrogen ion (H⁺) is released from the carboxyl group, and the resulting anion is the propanoate ion (C₂H₅COO⁻).
💧 Reaction of C₂H₅COOH Showing Hydronium Ion (H₃O⁺) as Product
Including water as the base, the proton binds with H₂O to form hydronium:
C₂H₅COOH (aq) + H₂O (l) ⇌ H₃O⁺ (aq) + C₂H₅COO⁻ (aq)
This is the preferred depiction in most acid-base chemistry discussions involving aqueous systems.
🔍 Summary Table
| Acid | Reaction Showing H⁺ | Reaction Showing H₃O⁺ |
|---|---|---|
| HBrO₂ | HBrO₂ ⇌ H⁺ + BrO₂⁻ | HBrO₂ + H₂O ⇌ H₃O⁺ + BrO₂⁻ |
| C₂H₅COOH | C₂H₅COOH ⇌ H⁺ + C₂H₅COO⁻ | C₂H₅COOH + H₂O ⇌ H₃O⁺ + C₂H₅COO⁻ |
🧠 Key Insight
Both HBrO₂ and C₂H₅COOH are weak acids and do not fully dissociate in water. The difference between writing H⁺ or H₃O⁺ lies in whether you explicitly show water accepting the proton. H₃O⁺ is more chemically accurate in aqueous solutions, but both notations are commonly accepted depending on context.
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