Answer
Main group = elements whose valence shell involves only s or p subshells (Groups 1ā2, 13ā18).
- Configuration A (
[Ne] 3s¹) corresponds to Na, an s-block metal. - Configuration C (
[Kr] 4d10 5s2 5p5) is I (iodine), a p-block halogen.
Configurations B and D possess 3d electrons, and E (Th) has 6d/5f involvement ā so none are main-group.
Therefore, the only main-group configurations listed are A and C, making Option 2 the correct choice.